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Download e-book for kindle: A Critical Review of Equilibrium Data for Proton and Metal by W.A. E. McBryde

By W.A. E. McBryde

ISBN-10: 0080223443

ISBN-13: 9780080223445

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Additional info for A Critical Review of Equilibrium Data for Proton and Metal Complexes of 1,10–phenanthroline, 2,2'–Bipyridyl and Related Compounds. Critical Evaluation of Equilibrium Constants in Solution: Stability Constants of Metal Complexes

Sample text

38 EtOH B2 1 3 . 1 KNO3 25 25% aq. MeOH 50% aq. MeOH 75% aq. 78 14 68N 25% aq. EtOH 50% aq. EtOH 75% aq. 59 14 68N 25% aq. 69 14 7 ON 50% aq. 66 75% aq. 77 i>2 1 3 . 3 Metal ion (Continued) Medium Temp. °C Cd(II) log Ki log K 2 log K 3 log 3 3 25% aq. 85 50% aq. 53 75% aq. 3 Metal ion (Continued) Temp. 38 (15^5) 12Dt Reference 4,7 - Diphenylphenanthroline V(II) ? 20 V20-+-+- ? 3 Metal ion (Continued) Temp. 3 KNO3 16 61J 12 61H 4-Chloro-2-Methylphenanthroline Fe(II) - EtOH, 0 . 9 5-Chlorophenanthroline Ni(II) 25 50% EtOH, 0 .

PH PH < t . PH PH < t r->~ CN rH CM O rH O ·-> o I J- U as vO rJ vO \o m o o r». m σ> LO o cd S3 O CM CM O co o O m m Os vO vO vO CN CM CM CT> rH O O VO vO m o r»·.

6% aq. 2 Temp. PKi Temp. 34 20 20% aq. 62 25 50% aq. 47 25 50% aq. 41 25 50% aq. 58 25 50% aq. 94 25 75% aq. 40 25 50% aq. 97 25 50% aq. l (Continued) Substituent Unsubstituted pKi Method Reference 25 25% aq. n-PrOH 50% aq. n-PrOH 75% aq. 58 25 25% aq. Me 2 CO 50% aq. M e 2 C 0 75% aq. 2 7 ON 25 25 25 25 25 25 25 25 25 25 Aq. 001 I 8% aq. 4% aq. 3% aq. 4% aq. 0% aq. 1% aq. 7% aq. 0% aq. 6% aq. 2 Temp. PKi Temp. 34 20 20% aq. 62 25 50% aq. 47 25 50% aq. 41 25 50% aq. 58 25 50% aq. 94 25 75% aq. 40 25 50% aq.

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A Critical Review of Equilibrium Data for Proton and Metal Complexes of 1,10–phenanthroline, 2,2'–Bipyridyl and Related Compounds. Critical Evaluation of Equilibrium Constants in Solution: Stability Constants of Metal Complexes by W.A. E. McBryde


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